82Nano Coatings a Solution for Corrosion: A Review


Corrosion protection of the metal is one the most serious problems that mankind has to face. In order to reduce corrosion impact and increase service life of metallic structures protective coatings are applied. Nano coatings are important due to their unique properties that may lead to new and exciting application in corrosion preventing. Nano coatings have several advantages such as better surface appearance, good chemical resistance, better thermal and electrical conductivity and better corrosion resistance. Improvements in environmental impact can be achieved utilizing nanostructure particles in coating and eliminating the requirement of toxic solvents. This review highlights the most recent trends in the field of nano coatings for corrosion protection of metallic materials in a wide range of technical applications.

Keywords: Nano coating, Polymer coating, Self-cleaning coating, Self-healing coating


  • M.F. Montemor, Functional and smart coatings for corrosion protection: a review of recent advances, Surface & Coatings Technology, (2014), doi: 10.1016/j.surfcoat.2014.06.031.

  • D. G. Shchukin, S. V. Lamaka, K. A. Yasakau, M. L. Zheludkevich, M. G. S. Ferreira, and H. Mo1hwald, Active Anticorrosion Coatings with Halloysite Nanocontainers, J. Phys. Chem. 112 (2008) 958-964.

  • K. J. Jothi, K.Palanivelu, Synergistic effect of silane modified nanocomposites for active corrosion protection, Ceramics International 39(2013)7619–7625.

  • K.A. Yasakau, S. Kallip, M.L. Zheludkevich, M.G.S. Ferreira, Active Corrosion Protection of AA2024 by sol–gel Coatings with Cerium molybdate nanowires, Electrochimica Acta 112 (2013) 236– 246, DOI: 10.1016/j.electacta.2013.08.126.

  • P. P. Mahulikar, R. S. Jadhav, and D. G. Hundiwale, Performance of Polyaniline/TiO2 Nanocomposites in Epoxy for Corrosion Resistant Coatings, Iranian Polymer Journal, 20 (5) ( 2011) 367-376.

  • R. B. Figueira, C. J. R. Silva, E. V. Pereira, Organic–inorganic hybrid sol–gel coatings for metal corrosion protection: a review of recent progress, J. Coat. Technol. Res., 12 (1) (2015)1–35.

  • K. Tao, X. Zhou, H. Cui and J. Zhang, Preparation and Properties of a Nanostructured NiCrC Alloy Coating for Boiler Tubes Protection, Materials Transactions, 49-9 (2008) 2159-2162.

  • M.S. Donley, V.N. Balbyshev, N.N. Voevodin, Self-assembled NAnophase Particle (SNAP) surface treatments forcorrosion protection of AA2024-T3, Progress in Organic Coatings, 52 (2005) 34–38.

  • R. Joseph Rathish, R. Dorothy, R. M. Joany, M. Pandiarajan and Susai Rajendran, Corrosion Resistance of Nanoparticle -Incorporated Nano Coatings, Eur. Chem. Bull., 2013, 2(12), 965-970.

  • N. P. Tavandashti, S. Sanjabi and T. Shahrabi, Evolution of corrosion protection performance of hybrid silica based sol–gel nanocoatings by doping inorganic inhibitor, Materials and Corrosion, 62-5 (2011) 411-415.

  • M. L. Zheludkevich, D. G. Shchukin, K. A. Yasakau, H. Mohwald, and M. G. S. Ferreira, Anticorrosion Coatings with Self-Healing Effect Based on Nanocontainers Impregnated with Corrosion Inhibitor, Chem. Mater. 19 (2007) 402-411.

  • E. Abdullayev, V. Abbasov, A. Tursunbayeva, V. Portnov, H. Ibrahimov, G. Mukhtarova, and Y. Lvov, Self-Healing Coatings Based on Halloysite Clay Polymer Composites for Protection of Copper Alloys, ACS Appl. Mater. Interfaces, 5(2013) 4464−4471, DOI: 10.1021/am400936m.

  • A. Hikasa, T. Sekino, Y. Hayashi, R. Rajagopalan, K. Niihara, Preparation And Corrosion Studies Of Self-Healing Multi-Layered Nano Coatings of Silica And Swelling Clay, Mat Res Innovat., 8.2:84-88 (2003) 1432-8917.

  • J. Tedim, M. L. Zheludkevich, A. N. Salak, A. Lisenkov and M. G. S. Ferreira, Nanostructured LDH-Container Layer with Active Protection Functionality, J. Mater. Chem., 21(2011) 15464–15470.

  •  Y. M. Lvov, D. G. Shchukin, H. Mohwald, and Ronald R. Price, Halloysite Clay Nanotubes for Controlled Release of Protective Agents, Perspective, 2(5) (2008) 814-820,DOI: 10.1021/nn800259q CCC.

  • Y. Lea, P. Houa, J. Wanga, J. F. Chena, Controlled release active antimicrobial corrosion coatings with Ag/SiO2 core–shell nanoparticles, Materials Chemistry and Physics 120 (2010) 351–355, DOI:10.1016/j.matchemphys.2009.11.020.

  • D. G. Shchukin, and H. Möhwald, Self-Repairing Coatings Containing Active Nanoreservoirs. Small, 3(2007) 926–943. doi:10.1002/smll.200700064.

  • F. Feil, W. Fu¨rbeth and M. Schutze, Nanoparticle based inorganic coatings for corrosion protection of magnesium alloys, Surface Engineering, 24 (2008) 198-203, DOI 10.1179/174329408X282550.

  • A. Michalik and M. Rohwerder, Conducting Polymers for Corrosion Protection: A Critical View, Z. Phys. Chem., 219 (2005) 1547–1559.

  • M. G. Hosseini, R. Bagheri, R. Najjar, Electropolymerization of Polypyrrole and Polypyrrole-ZnO Nanocomposites on Mild Steel and Its Corrosion Protection Performance, Journal of Applied Polymer Science, 121(2011) 3159–3166.

  • M. Selvaraj, S. Palraj, K. Maruthan, G. Rajagopal, G. Venkatachari, Synthesis and Characterization of Polypyrrole Composites for Corrosion Protection of Steel, Journal of Applied Polymer Science, 116 (2010) 1524–1537, DOI 10.1002/app.31430.